人类史上令人叹为观止的极限精度制造成果有哪些？ 老骥伏枥，材料&化学博士在读/NBA球迷一枚 作为一名化学搬砖狗一枚，我简单从无机合成化学的角度上说一下一些令人叹为观止的成果，学业不精，大家少拍砖~ 1 纳米空心结构&空心核壳结构 空心结构，尤其是氧化物的微尺度制备，南洋理工大学的 Xiongwen (David) Lou 教授的工作基本达到了我不是针对谁的程度，几乎能够作为艺术品来欣赏。 1）NiS nanoframes Yu X Y, Yu L, Wu H B, et al. Formation of Nickel Sulfide Nanoframes from Metal–Organic Frameworks with Enhanced Pseudocapacitive and Electrocatalytic Properties[J]. Angewandte Chemie, 2015, 127(18): 5421-5425. 2）ZnMn2O4 Multi-Shelled Hollow Spheres Zhang G, Lou X W D. General Synthesis of Multi‐Shelled Mixed Metal Oxide Hollow Spheres with Superior Lithium Storage Properties[J]. Angewandte Chemie, 2014, 126(34): 9187-9190. 3）NiCo2O4 Hollow Spheres Shen L, Yu L, Yu X Y, et al. Self‐Templated Formation of Uniform NiCo2O4 Hollow Spheres with Complex Interior Structures for Lithium‐Ion Batteries and Supercapacitors[J]. Angewandte Chemie International Edition, 2015, 54(6): 1868-1872. 4）Co nanoparticle-embedded carbon@Co9S8 double-shelled nanocages Hu H, Han L, Yu M, et al. Metal–organic-framework-engaged formation of Co nanoparticle-embedded carbon@ Co 9 S 8 double-shelled nanocages for efficient oxygen reduction[J]. Energy & Environmental Science, 2016. 5）MoS 2 microboxes constructed by nanosheets Zhang L, Wu H B, Yan Y, et al. Hierarchical MoS 2 microboxes constructed by nanosheets with enhanced electrochemical properties for lithium storage and water splitting[J]. Energy & Environmental Science, 2014, 7(10): 3302-3306. 6）Manganese Sulfide Microboxes Zhang L, Zhou L, Wu H B, et al. Unusual Formation of Single‐Crystal Manganese Sulfide Microboxes Co‐mediated by the Cubic Crystal Structure and Shape[J]. Angewandte Chemie, 2012, 124(29): 7379-7382. 7）SnO2 and TiO2 Hollow Nanostructures Wang Z, Wang Z C, Madhavi S, et al. One‐Step Synthesis of SnO2 and TiO2 Hollow Nanostructures with Various Shapes and Their Enhanced Lithium Storage Properties[J]. Chemistry-A European Journal, 2012, 18(24): 7561-7567. 8）Fe2O3 microboxes Zhang L, Wu H B, Madhavi S, et al. Formation of Fe2O3 microboxes with hierarchical shell structures from metal–organic frameworks and their lithium storage properties[J]. Journal of the American Chemical Society, 2012, 134(42): 17388-17391. 2 一维纳米线&管&棒结构 一维尺度的纳米结构，好的工作有很多，分布领域也比较广，而且绝大多数的金属氧化物都可以得到该形貌，其中近期做的比较好的是武汉理工大学的 Liqiang Mai （麦立强）教授 1）CuO/CoOcore/shellheterostructurearrays Wang J, Zhang Q, Li X, et al. Smart construction of three-dimensional hierarchical tubular transition metal oxide core/shell heterostructures with high-capacity and long-cycle-life lithium storage[J]. Nano Energy, 2015, 12: 437-446. 2）Na1.25V3O8 nanowires Dong Y, Li S, Zhao K, et al. Hierarchical zigzag Na 1.25 V 3 O 8 nanowires with topotactically encoded superior performance for sodium-ion battery cathodes[J]. Energy & Environmental Science, 2015, 8(4): 1267-1275. 3) VO2 nanowires assembled into hollow microspheres Niu C, Meng J, Han C, et al. VO2 nanowires assembled into hollow microspheres for high-rate and long-life lithium batteries[J]. Nano letters, 2014, 14(5): 2873-2878. 4) SnO 2–PANI nanorod arrays Xu W, Zhao K, Niu C, et al. Heterogeneous branched core–shell SnO 2–PANI nanorod arrays with mechanical integrity and three dimentional electron transport for lithium batteries[J]. Nano Energy, 2014, 8: 196-204. 5) β-AgVO3 nanowire clusters Han C, Pi Y, An Q, et al. Substrate-assisted self-organization of radial β-AgVO3 nanowire clusters for high rate rechargeable lithium batteries[J]. Nano letters, 2012, 12(9): 4668-4673. 3 三维有序结构 三位有序结构的制备是一门技术活，其中复旦大学赵东元教授在介孔材料领域的工作是世界级的成果，但介于三位有序领域涵盖的范围比较广，此处列出一些代表性的工作 1）3D ordered macroporous LaFeO3 Xu J J, Wang Z L, Xu D, et al. 3D ordered macroporous LaFeO 3 as efficient electrocatalyst for Li–O 2 batteries with enhanced rate capability and cyclic performance[J]. Energy & Environmental Science, 2014, 7(7): 2213-2219. 2）Mesoporous silica Zhao D, Feng J, Huo Q, et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores[J]. science, 1998, 279(5350): 548-552. 3）赵东元院士的漂亮工作太多，此处就不详细描述了，贴一些图大家看看吧 这里列举的一些微观化学合成方法和技术，和传统意义上的机械、微电子制造等领域不太一样，是一种自下而上的调控，希望能给大家不一样的理解和视野！ 查看知乎原文
